|
|
malonate_semialdehyde + CoA + NAD+ <=> acetyl-CoA + CO2 + NADH
|
1.2.1.18
malonate-semialdehyde dehydrogenase (acetylating)
1.2.1.27
methylmalonate-semialdehyde dehydrogenase (CoA-acylating)
|
–
–
|
| |
BRENDA:
BR29389-a
KEGG:
R00705
MetaCyc:
RXN-2902;
RXN-9958_WOP
SABIO-RK:
1081
|
|
|
|
3D-3,5/4-trihydroxycyclohexa-1,2-dione + H2O <=> 5-deoxy-D-glucuronate + H+
|
3.7.1.22
3D-(3,5/4)-trihydroxycyclohexane-1,2-dione acylhydrolase (ring-opening)
|
–
|
| |
BRENDA:
BR50997
KEGG:
R08603
MetaCyc:
RXN-14149
|
|
|
|
5-dehydro-2-deoxy-D-gluconate + ATP <=> H+ + 6-phospho-5-dehydro-2-deoxy-D-gluconate + ADP
|
2.7.1.92
5-dehydro-2-deoxygluconokinase
|
–
|
| |
BRENDA:
BR47816
KEGG:
R05661
MetaCyc:
5-DEHYDRO-2-DEOXYGLUCONOKINASE-RXN
|
|
|
|
5-deoxy-D-glucuronate <=> 5-dehydro-2-deoxy-D-gluconate
|
5.3.1.30
5-deoxy-glucuronate isomerase
|
–
|
| |
BRENDA:
BR51006
KEGG:
R08503
MetaCyc:
RXN-14150
|
|
|
|
scyllo-inosose <=> H2O + 3D-3,5/4-trihydroxycyclohexa-1,2-dione
|
4.2.1.44
myo-inosose-2 dehydratase
|
–
|
| |
BRENDA:
BR423;
BS1987
KEGG:
R02782;
R05659
MetaCyc:
MYO-INOSOSE-2-DEHYDRATASE-RXN
|
|
|
|
myo-inositol + NAD+ <=> scyllo-inosose + NADH + H+
|
1.1.1.114
apiose 1-reductase
1.1.1.18
inositol 2-dehydrogenase
|
–
–
|
| |
BRENDA:
BR36703;
BS187060
KEGG:
R01183
MetaCyc:
MYO-INOSITOL-2-DEHYDROGENASE-RXN
SABIO-RK:
1420
|
|
|
|
6-phospho-5-dehydro-2-deoxy-D-gluconate <=> malonate_semialdehyde + dihydroxyacetone_phosphate
|
4.1.2.29
5-dehydro-2-deoxyphosphogluconate aldolase
|
–
|
| |
BRENDA:
BR361
KEGG:
R05378
MetaCyc:
4.1.2.29-RXN
|
|
